Determination of Chromium (III) and Chromium (VI) Using Flow Injection Coupled with Flame Atomic Absorption Spectrometry and Direct Current Plasma Technique

Abstract

Micro column of activated alumina was used in Flow Injection coupled with Flame Atomic Absorption and Direct Current Plasma Atomic Emission Spectrometry (DCPAES), for the determination of Cr+3 and Cr+6 in samples of groundwater used for drinking purposes, from different localities, and dust samples from elementary schools of west of Tripoli area. Atomic signals for both species Cr+3 and Cr+6 were analyzed by (FIFAAS) with limited detection of 0.03 µg/ml, while in DCPAES it was 0.003 µg/ml and 0.002 µg/ml for Cr+3 and Cr+6 respectively. Concentration data obtained for potable water for Cr+3 and Cr+6 were found less than the detection limit of both instruments, and concentration data of dust samples for Cr+3 was in the range of 0.9 - 1.5 µg/ml whereas Cr+6 was less than 0.05 µg/ml when analyses by DCPAES were used. The results obtained provided evidence that water samples collected from the above mentioned sources were free from any presence of chromium metal.

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